H2O2/Tf2O system:: An efficient oxidizing reagent for selective oxidation of sulfanes

被引：38

作者：

Khodaei, Mohammad Mehdi ^{[1
,2
]}

Bahrami, Kiumars ^{[1
,2
]}

Karimi, Ahmad ^{[1
,2
]}

机构：

[1] Razi Univ, Dept Chem, Kermanshah 67149, Iran

[2] Razi Univ, Nanosci & Nanotechnol Res Ctr, Kermanshah 67149, Iran

来源：

SYNTHESIS-STUTTGART | 2008年 / 11期

关键词：

sulfoxides; chemoselectivity; environmentally friendly; triflic anhydride;

D O I：

10.1055/s-2008-1067019

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A versatile procedure for the oxidation of sulfanes to sulfoxides without any overoxidation to sulfones has been reported. It is noteworthy that the reaction tolerates oxidatively sensitive functional groups and that the sulfur atom is selectively oxidized.

引用

页码：1682 / 1684

页数：3

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