Alternative sets of hyperspherical harmonics: Satisfying cusp conditions through frame transformations

By extending the concept of Euler-angle rotations to more than three dimensions, we develop the systematics under rotations in higher-dimensional space for a novel set of hyperspherical harmonics. Applying this formalism, we determine all pairwise Coulomb interactions in a few-body system without recourse to multipole expansions. Our approach combines the advantages of relative coordinates with those of the hyperspherical description. In the present method, each Coulomb matrix element reduces to the "1/r'' form familiar from the two-body problem. Consequently, our calculation accounts for all the cusps in the wave function whenever an interparticle separation vanishes. Unlike a truncated multipole expansion, the calculation presented here is exact. Following the systematic development of the procedure for an arbitrary number of particles, we demonstrate it explicitly with the simplest nontrivial example, the three-body system. (C) 1999 American Institute of Physics. [S0022-2488(99)02804-2].