(1,1,1,5,5,5-hexafluoro-2,4-pentanedionato-O,O′)(1,4,7,10,13-pentaoxapentadecane-κ5O)-sodium

被引：11

作者：

Farrugia, LJ ^{[1
]}

Watson, IM

机构：

[1] Univ Glasgow, Dept Chem, Glasgow G12 8QQ, Lanark, Scotland

[2] Univ Strathclyde, Wolfson Ctr, Inst Photon, Glasgow G4 0NW, Lanark, Scotland

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198013031

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title compound, [Na(C5HF6O2)(C10H20O5)], contains a seven-coordinate Na+ ion with an irregular coordination geometry. It is bonded to the five crown ether and the two beta-diketonate O atoms. The structure contains no unusual features, the conformation of the crown ether being very similar to those in compounds described previously. There are no particularly short intermolecular contacts and the title compound behaves as a discrete molecule, which probably accounts for its relatively high volatility.

引用

页码：326 / 328

页数：3

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