Nucleation, growth and characterization of nanocrystalline diamond films

被引:46
作者
Cicala, G
Bruno, P
Bénédic, F
Silva, F
Hassouni, K
Senesi, GS
机构
[1] CNR, Sez Bari, IMIP, I-70126 Bari, Italy
[2] Univ Bari, Dept Chem, I-70126 Bari, Italy
[3] Univ Paris 13, CNRS, UPR 1311, LIMHP, F-93430 Villetaneuse, France
关键词
nanocrystalline; diamond film; nucleation; plasma CVD;
D O I
10.1016/j.diamond.2004.12.025
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The growth of nanocrystalline diamond films has been obtained by microwave plasmas fed with CH4/Ar/H-2 mixtures. This study seeks to provide an insight on the effects of diamond powder size used for ultrasonical abrasion of silicon substrates, varied from 0.125 to 45 mu m, on nucleation density, growth rate and quality of the films. It has been found that large diamond powder size strongly enhances the nucleation density and reduces the surface roughness of thin and thick films. The effect of diamond powder size is negligible on the growth rate and the bulk properties of the films such as structure, crystallinity and phase composition. (c) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码:421 / 425
页数:5
相关论文
共 18 条
[1]   In situ optical characterization during MPACVD diamond film growth on silicon substrates using a bichromatic infrared pyrometer under oblique incidence [J].
Bénédic, F ;
Belmahi, H ;
Easwarakhanthan, T ;
Alnot, P .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 2001, 34 (07) :1048-1058
[2]  
BRUNO P, IN PRESS THIN SOLID
[3]   Highly transparent nano-crystalline diamond films via substrate pretreatment and methane fraction optimization [J].
Chen, KH ;
Bhusari, DM ;
Yang, JR ;
Lin, ST ;
Wang, TY ;
Chen, LC .
THIN SOLID FILMS, 1998, 332 (1-2) :34-39
[4]   PREPARATION OF SMOOTH AND NANOCRYSTALLINE DIAMOND FILMS [J].
ERZ, R ;
DOTTER, W ;
JUNG, K ;
EHRHARDT, H .
DIAMOND AND RELATED MATERIALS, 1993, 2 (2-4) :449-453
[5]   Origin of the 1150-cm-1 Raman mode in nanocrystalline diamond -: art. no. 121405 [J].
Ferrari, AC ;
Robertson, J .
PHYSICAL REVIEW B, 2001, 63 (12)
[6]   Nanocrystalline diamond films [J].
Gruen, DM .
ANNUAL REVIEW OF MATERIALS SCIENCE, 1999, 29 :211-259
[7]   Study on enhancement of diamond nucleation on fused silica substrate by ultrasonic pretreatment [J].
Hao, TL ;
Shi, CR .
DIAMOND AND RELATED MATERIALS, 2004, 13 (03) :465-472
[8]   Self-consistent microwave field and plasma discharge simulations for a moderate pressure hydrogen discharge reactor [J].
Hassouni, K ;
Grotjohn, TA ;
Gicquel, A .
JOURNAL OF APPLIED PHYSICS, 1999, 86 (01) :134-151
[9]   Deposition of ballas diamond and nano-crystalline diamond [J].
Haubner, R ;
Lux, B .
INTERNATIONAL JOURNAL OF REFRACTORY METALS & HARD MATERIALS, 2002, 20 (02) :93-100
[10]   CORRELATION BETWEEN NUCLEATION SITE DENSITY AND RESIDUAL DIAMOND DUST DENSITY IN DIAMOND FILM DEPOSITION [J].
IHARA, M ;
KOMIYAMA, H ;
OKUBO, T .
APPLIED PHYSICS LETTERS, 1994, 65 (09) :1192-1194