An optimized kinetic model of H2/CO combustion

被引：584

作者：

Davis, SG

Joshi, AV

Wang, H

Egolfopoulos, F

机构：

[1] Univ Delaware, Dept Mech Engn, Newark, DE 19716 USA

[2] Univ So Calif, Dept Aerosp & Mech Engn, Los Angeles, CA 90089 USA

来源：

PROCEEDINGS OF THE COMBUSTION INSTITUTE | 2005年 / 30卷 / 01期

基金：

美国国家科学基金会;

关键词：

kinetics; detailed reaction model; hydrogen; carbon monoxide;

D O I：

10.1016/j.proci.2004.08.252

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

We propose a H-2-CO kinetic model which incorporates the recent thermodynamic, kinetic, and species transport updates relevant to high-temperature H-2 and CO oxidation. Attention has been placed on obtaining a comprehensive and kinetically accurate model able to predict a wide variety of H-2-CO combustion data. The model was subject to systematic optimization and validation tests against reliable H-2-CO combustion data, from global combustion properties (shock-tube ignition delays, laminar flame speeds, and extinction strain rates) to detailed species profiles during H-2 and CO oxidation in flow reactor and in laminar premixed flames. (c) 2004 The Combustion Institute. Published by Elsevier Inc. All rights reserved.

引用

页码：1283 / 1292

页数：10

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