Solid phase synthesis of cyclopropenes

被引：13

作者：

Cano, M ^{[1
]}

Camps, F ^{[1
]}

Joglar, J ^{[1
]}

机构：

[1] CSIC, Cid, Dept Biol Organ Chem, ES-08034 Barcelona, Spain

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 52期

关键词：

D O I：

10.1016/S0040-4039(98)02241-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Cyclopropene derivatives of high purity were prepared by reaction of acetylenes with a rhodium carbenoid bound to a polystyrene resin. This solid phase method avoids the formation of undesired byproducts obtained in the corresponding solution reaction and an eventual extension to combinatorial synthesis of cyclopropene derivatives could be achieved. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：9819 / 9822

页数：4

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