Fluorous bulk membranes for potentiometric sensors with wide selectivity ranges:: Observation of exceptionally strong ion pair formation

被引：85

作者：

Boswell, PG ^{[1
]}

Bühlmann, P ^{[1
]}

机构：

[1] Univ Minnesota, Dept Chem, Minneapolis, MN 55455 USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2005年 / 127卷 / 25期

关键词：

D O I：

10.1021/ja052403a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Potentiometric sensors based on fluorous membranes doped with a fluorophilic tetraphenylborate derivative are shown to have a remarkably wide range of selectivities that exceeds the selectivity range of conventional polymeric membranes by 8 orders of magnitude. The fluorous character of these sensing membranes explains the formation of ion pairs of unprecedented strength. Ion pair formation constants in perfluoroperhydrophenanthrene, as measured in this work, are on the order of 1020 and exceed previously reported values for ion pair formation in nonpolar solvents by 6 orders of magnitude. The low solubility of lipids in such fluorous phases makes them very promising for the reduction of biofouling. Copyright © 2005 American Chemical Society.

引用

页码：8958 / 8959

页数：2

共 38 条

[1] Tetrakis(decyl)ammonium tetraphenylborate: A novel electrolyte for non-polar media [J].