Composition and shape control of crystalline Ca1-xSrxTiO3 perovskite nanoparticles

被引：58

作者：

Mao, YB

Wong, SS ^{[1
]}

机构：

[1] SUNY Stony Brook, Dept Chem, Stony Brook, NY 11794 USA

[2] Brookhaven Natl Lab, Dept Chem & Mat Sci, Upton, NY 11973 USA

来源：

ADVANCED MATERIALS | 2005年 / 17卷 / 18期

关键词：

D O I：

10.1002/adma.200500437

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The synthesis and composition of crystalline Ca1-xSr xTiO3 perovskite nanoparticles were discussed. The molten salt synthesis (MSS) method, in which a solid-state reaction takes place between metal oxalates and anatase TiO2 in a molten NaCl medium at 820°C in the presence of a nonionic surfactant, was used for the purpose. The composition of the resulting nanoparticles is tunable by adjusting the ratio of the reactants. The crystallinity and purity of the five as-synthesized CST samples were detected using powder X-ray diffraction (XRD) technique.

引用

收藏

页码：2194 / 2199

页数：6

相关论文

共 39 条

[1] Molten salt synthesis of the lead titanate PbTiO3, investigation of the reactivity of various titanium and lead salts with molten alkali-metal nitrites [J].

Aboujalil, A ;

Deloume, JP ;

Chassagneux, F ;

Scharff, JP ;

Durand, B .

JOURNAL OF MATERIALS CHEMISTRY, 1998, 8 (07) :1601-1606

[2] Ferroelectricity at the nanoscale: Local polarization in oxide thin films and heterostructures [J].

Ahn, CH ;

Rabe, KM ;

Triscone, JM .

SCIENCE, 2004, 303 (5657) :488-491

[3] Semiconductor clusters, nanocrystals, and quantum dots [J].

Alivisatos, AP .

SCIENCE, 1996, 271 (5251) :933-937

[4] Structures in the system CaTiO3/SrTiO3 [J].

Ball, CJ ;

Begg, BD ;

Cookson, DJ ;

Thorogood, GJ ;

Vance, ER .

JOURNAL OF SOLID STATE CHEMISTRY, 1998, 139 (02) :238-247

[5] Recent advances in the liquid-phase syntheses of inorganic nanoparticles [J].

Cushing, BL ;

Kolesnichenko, VL ;

O'Connor, CJ .

CHEMICAL REVIEWS, 2004, 104 (09) :3893-3946

[6] PREPARATION OF ROD-SHAPED BATIO3 POWDER [J].

HAYASHI, Y ;

KIMURA, T ;

YAMAGUCHI, T .

JOURNAL OF MATERIALS SCIENCE, 1986, 21 (03) :757-762

[7]

Hill NA, 2000, J PHYS CHEM B, V104, P6694, DOI [10.1021/jp000114x, 10.1021/jpc00114x]

[8] Vibrational spectroscopy and x-ray diffraction of Perovskite compounds Sr(1-x)M(x)TiO(3) (M=Ca,Mg; 0<=x<=1) [J].

Hirata, T ;

Ishioka, K ;

Kitajima, M .

JOURNAL OF SOLID STATE CHEMISTRY, 1996, 124 (02) :353-359

[9] Preparation and thermal decomposition of various forms of strontium oxalate [J].

Knaepen, E ;

Mullens, J ;

Yperman, J ;

VanPoucke, LC .

THERMOCHIMICA ACTA, 1996, 284 (01) :213-227

[10] Decomposition of carbon dioxide by the dielectric barrier discharge (DBD) plasma using Ca0.7Sr0.3TiO3 barrier [J].

Li, RX ;

Tang, Q ;

Yin, S ;

Yamaguchi, Y ;

Sato, T .

CHEMISTRY LETTERS, 2004, 33 (04) :412-413

← 1 2 3 4 →