Origin of the deactivation in styrene aziridination by aryl azides, catalyzed by ruthenium porphyrin complexes.: Structural characterization of a Δ2-1,2,3-triazoline RuII(TPP)CO complex

被引：43

作者：

Fantauzzi, S

Gallo, E

Caselli, A

Ragaini, F

Macchi, P

Casati, N

Cenini, S ^{[1
]}

机构：

[1] Univ Milan, Dipartimento Chim Inorgan Met Organ & Analit, Milan, Italy

[2] CNR, ISTM, I-20133 Milan, Italy

[3] Univ Milan, Dipartimento Chim Strutt & Stereochim, I-20133 Milan, Italy

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 20期

关键词：

D O I：

10.1021/om050244y

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The reaction of Ru(TPP)CO (TPP = dianion of tetraphenylporphyrin) with 1-(p-nitrophenyl)-5-methyl-5-phenyl- 1,2,3-triazoline yielded a Delta(2)-1,2,3-triazoline ruthenium(II) porphyrin complex, which is responsible for the catalyst deactivation in the aziridination reaction of (x-methylstyrene by p-nitrophenyl azide.

引用

页码：4710 / 4713

页数：4

共 33 条

[11] METALLOPORPHYRINS CONTAINING SIGMA-BONDED NITROGEN AXIAL LIGANDS .2. SYNTHESIS AND CHARACTERIZATION OF IRON(III) TETRAZOLATO AND TRIAZOLATO PORPHYRIN COMPLEXES - MOLECULAR-STRUCTURE OF (5-METHYLTETRAZOLATO)(2,3,7,8,12,13,17,18-OCTAETHYLPORPHINATO)IRON(III) [J].