A Luminescent Molecular Thermometer for Long-Term Absolute Temperature Measurements at the Nanoscale

被引:425
作者
Brites, Carlos D. S. [3 ,4 ]
Lima, Patricia P. [3 ,4 ]
Silva, Nuno J. O. [3 ,4 ]
Millan, Angel [1 ,2 ]
Amaral, Vitor S. [3 ,4 ]
Palacio, Fernando [1 ,2 ]
Carlos, Luis D. [3 ,4 ]
机构
[1] Univ Zaragoza, CSIC, Dept Fis Mat Condensada, Fac Ciencias, E-50009 Zaragoza, Spain
[2] Univ Zaragoza, Inst Ciencia Mat Aragon, E-50009 Zaragoza, Spain
[3] Univ Aveiro, Dept Fis, P-3810193 Aveiro, Portugal
[4] Univ Aveiro, CICECO, P-3810193 Aveiro, Portugal
关键词
ORGANIC-INORGANIC HYBRIDS; PHOSPHOR; FLUORESCENCE; NANOPARTICLES; EUROPIUM(III); SPECTROSCOPY; CONVERSION; LIFETIME; SENSORS;
D O I
10.1002/adma.201001780
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A unique Eu3+/Tb3+ luminescent self-referencing nanothermometer allowing absolute measurements in the 10-350 K temperature range and sub-micrometer spatial resolution is reported (see Figure). It has up to 4.9%K-1 temperature sensitivity and high photostability for long-term use. The combination of molecular thermometry, superparamagnetism and luminescence in a nanometric host matrix provides multifunctionality opening the way for new exciting applications. © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:4499 / 4504
页数:6
相关论文
共 37 条
[1]   AC thermal imaging of a microwire with a fluorescent nanocrystal: Influence of the near field on the thermal contrast [J].
Aigouy, Lionel ;
Saidi, Elika ;
Lalouat, Loic ;
Labeguerie-Egea, Jessica ;
Mortier, Michel ;
Loew, Peter ;
Bergaud, Christian .
JOURNAL OF APPLIED PHYSICS, 2009, 106 (07)
[2]   Fluorescence thermometer based on the photoluminescence intensity ratio in Tb doped phosphor materials [J].
Aizawa, H ;
Katsumata, T ;
Komuro, S ;
Morikawa, T ;
Ishizawa, H ;
Toba, E .
SENSORS AND ACTUATORS A-PHYSICAL, 2006, 126 (01) :78-82
[3]   Nanoscale thermometry via the fluorescence of YAG:Ce phosphor particles:: measurements from 7 to 77 °C [J].
Allison, SW ;
Gillies, GT ;
Rondinone, AJ ;
Cates, MR .
NANOTECHNOLOGY, 2003, 14 (08) :859-863
[4]   Remote thermometry with thermographic phosphors: Instrumentation and applications [J].
Allison, SW ;
Gillies, GT .
REVIEW OF SCIENTIFIC INSTRUMENTS, 1997, 68 (07) :2615-2650
[5]   Noncontact two-color luminescence thermometry based on intramolecular luminophore cyclization within an ionic liquid [J].
Baker, GA ;
Baker, SN ;
McCleskey, TM .
CHEMICAL COMMUNICATIONS, 2003, (23) :2932-2933
[6]  
Bermudez VD, 1999, CHEM MATER, V11, P569
[7]   Fine-tuning of the chromaticity of the emission color of organic-inorganic hybrids co-doped with EuIII, TbIII, and TmIII [J].
Carlos, LD ;
Ferreira, RAS ;
Rainho, JP ;
Bermudez, VD .
ADVANCED FUNCTIONAL MATERIALS, 2002, 12 (11-12) :819-823
[8]   Lanthanide-Containing Light-Emitting Organic-Inorganic Hybrids: A Bet on the Future [J].
Carlos, Luis D. ;
Ferreira, Rute A. S. ;
Bermudez, Veronica de Zea ;
Ribeiro, Sidney J. L. .
ADVANCED MATERIALS, 2009, 21 (05) :509-534
[9]   A dual fluorescence temperature sensor based on perylene/exciplex interconversion [J].
Chandrasekharan, N ;
Kelly, LA .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2001, 123 (40) :9898-9899
[10]   Review of temperature measurement [J].
Childs, PRN ;
Greenwood, JR ;
Long, CA .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2000, 71 (08) :2959-2978