Gold nanocrystal formation on viologen-functionalized polymeric nanospheres

被引:54
作者
Cen, L [1 ]
Neoh, KG [1 ]
Kang, ET [1 ]
机构
[1] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore
关键词
D O I
10.1002/adma.200500100
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Poly(vinylbenzyl chloride) (PVBC) nanospheres synthesized via emulsion polymerization are used as the substrate for subsequent attachment of viologen moieties. The viologen-functionalized nanospheres can undergo photoinduced reaction with gold ions resulting in the formation of well-dispersed gold nanocrystals with diameters ranging from a few nanometers (see Figure, left) to 15 nm (Figure, right).
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页码:1656 / +
页数:7
相关论文
共 34 条
[1]   Intrazeolite photochemistry .17. Zeolites as electron donors: Photolysis of methylviologen incorporated within zeolites [J].
Alvaro, M ;
Garcia, H ;
Garcia, S ;
Marquez, F ;
Scaiano, JC .
JOURNAL OF PHYSICAL CHEMISTRY B, 1997, 101 (16) :3043-3051
[2]   THE SYNTHESIS AND ELECTROCHEMICAL STUDY OF NEW ELECTROCHROMIC VIOLOGEN-BASED MATERIALS [J].
BARLTROP, JA ;
JACKSON, AC .
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1984, (03) :367-371
[3]   Tunable multiple plasmon resonance wavelengths response from multicomponent polymer-metal nanocomposite systems [J].
Biswas, A ;
Aktas, OC ;
Schürmann, U ;
Saeed, U ;
Zaporojtchenko, V ;
Faupel, F ;
Strunskus, T .
APPLIED PHYSICS LETTERS, 2004, 84 (14) :2655-2657
[4]  
Caseri W, 2000, MACROMOL RAPID COMM, V21, P705, DOI 10.1002/1521-3927(20000701)21:11<705::AID-MARC705>3.0.CO
[5]  
2-3
[6]   Surface functionalization technique for conferring antibacterial properties to polymeric and cellulosic surfaces [J].
Cen, L ;
Neoh, KG ;
Kang, ET .
LANGMUIR, 2003, 19 (24) :10295-10303
[7]   In situ formation of Au/Pt bimetallic colloids on polystyrene microspheres: Control of particle growth and morphology [J].
Chen, CW ;
Serizawa, T ;
Akashi, M .
CHEMISTRY OF MATERIALS, 2002, 14 (05) :2232-2239
[8]   Preparation of platinum colloids on polystyrene nanospheres and their catalytic properties in hydrogenation [J].
Chen, CW ;
Serizawa, T ;
Akashi, M .
CHEMISTRY OF MATERIALS, 1999, 11 (05) :1381-1389
[9]  
Chen M. M. Y., 2002, LANGMUIR, V18, P2413
[10]  
Cullity B. D., ELEMENTS XRAY DIFFRA