Influence of Fe and Co/Ni on carbon arc plasma and formation of fullerenes and nanotubes

被引:22
作者
Huczko, A
Lange, H
Sogabe, T
机构
[1] Warsaw Univ, Dept Chem, PL-02093 Warsaw, Poland
[2] Toyo Tanso Co Ltd, Kagawa 7691612, Japan
关键词
D O I
10.1021/jp002842q
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Carbon nanostructures (fullerenes: and nanotubes) were obtained using the carbon are technique employing homogeneous carbon-iron and carbon-cobart-nickel anodes. The influence of these catalysts on the are plasma was studied by optical emission spectroscopy to determine temperatures and C-2 radical content in the arc zone. The solid products were analyzed by spectrophotometry and mass spectrometry to determine the C-60 yield and relative mass distributions of the higher fullerenes, respectively. SEM and TEM techniques were used to affirm the presence of carbon nanotubes in the resulting soot product.
引用
收藏
页码:10708 / 10712
页数:5
相关论文
共 36 条
[11]  
Churilov G. N., 1997, ZH TEKH FIZ, V67, P142
[12]   Reactive thermal plasmas: ultrafine particle synthesis and coating deposition [J].
Fauchais, P ;
Vardelle, A ;
Denoirjean, A .
SURFACE & COATINGS TECHNOLOGY, 1997, 97 (1-3) :66-78
[13]   Fullerene formation in carbon arc: Electrode gap dependence and plasma spectroscopy [J].
Huczko, A ;
Lange, H ;
Byszewski, P ;
Poplawska, M ;
Starski, A .
JOURNAL OF PHYSICAL CHEMISTRY A, 1997, 101 (07) :1267-1269
[14]   SINGLE-SHELL CARBON NANOTUBES OF 1-NM DIAMETER [J].
IIJIMA, S ;
ICHIHASHI, T .
NATURE, 1993, 363 (6430) :603-605
[15]   HELICAL MICROTUBULES OF GRAPHITIC CARBON [J].
IIJIMA, S .
NATURE, 1991, 354 (6348) :56-58
[16]   Production of carbon nanotubes [J].
Journet, C ;
Bernier, P .
APPLIED PHYSICS A-MATERIALS SCIENCE & PROCESSING, 1998, 67 (01) :1-9
[17]  
KRATSCHMER W, 1991, NATURE, V354, P54
[18]   C-60 - BUCKMINSTERFULLERENE [J].
KROTO, HW ;
HEATH, JR ;
OBRIEN, SC ;
CURL, RF ;
SMALLEY, RE .
NATURE, 1985, 318 (6042) :162-163
[19]   Carbon-iron arc plasma: Characterization and novel applications [J].
Lange, H ;
Huczko, A ;
Noworyta, K ;
Byszewski, P .
CZECHOSLOVAK JOURNAL OF PHYSICS, 1999, 49 (06) :933-940
[20]   Temperatures and C2 column densities in a carbon arc plasma [J].
Lange, H ;
Saidane, K ;
Razafinimanana, M ;
Gleizes, A .
JOURNAL OF PHYSICS D-APPLIED PHYSICS, 1999, 32 (09) :1024-1030