Crumpled Graphene Nanosheets as Highly Effective Barrier Property Enhancers

被引:442
作者
Compton, Owen C. [1 ]
Kim, Soyoung [2 ]
Pierre, Cynthia [3 ]
Torkelson, John M. [2 ,3 ]
Nguyen, SonBinh T. [1 ]
机构
[1] Northwestern Univ, Dept Chem, Evanston, IL 60208 USA
[2] Northwestern Univ, Dept Chem & Biol Engn, Evanston, IL 60208 USA
[3] Northwestern Univ, Dept Mat Sci & Engn, Evanston, IL 60208 USA
基金
美国国家科学基金会;
关键词
POLYIMIDE-CLAY HYBRID; NANOCOMPOSITE MEMBRANES; POLYMER/CLAY NANOCOMPOSITES; OPTICAL-PROPERTIES; FILMS; SHEETS; OXIDE; PERMEABILITY; DISPERSION; DIFFUSION;
D O I
10.1002/adma.201000960
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Near-trace concentrations (0.02 vol%) of crumpled graphene nanosheets suspended within a polystyrene matrix drastically inhibit the permeation of oxygen molecules through the resulting polymer-graphene nanocomposite. This decrease in permeability is a direct result of the low solubility of oxygen within the nanocomposite, which is considerably densified by the graphene.
引用
收藏
页码:4759 / +
页数:6
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