[V(η5-C5H5)]2C8H6:: a bimetallic pentalene-bridged complex with multiple bonding between the metal atoms

被引：29

作者：

Jones, SC ^{[1
]}

O'Hare, D ^{[1
]}

机构：

[1] Univ Oxford, Inorgan Chem Lab, Oxford OX1 3QR, England

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 17期

关键词：

D O I：

10.1039/b306688f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The bimetallic complex [V(Cp)](2)Pn, containing a V - V triple bond, has been synthesised; the vanadium centres adopt a syn-coordination and the complex exhibits a high-spin/low-spin equilibrium in both solution and the solid-state.

引用

页码：2208 / 2209

页数：2

共 17 条

[1] COOPERATIVE EFFECTS IN PI-LIGAND BRIDGED BINUCLEAR COMPLEXES .8. CYCLIC VOLTAMMETRIC, NMR, AND ESR SPECTROSCOPIC STUDIES OF ELECTRON-POOR SYNFACIAL BIS((ETA-5-CYCLOPENTADIENYL)METAL) MU-CYCLOOCTATETRAENE COMPLEXES OF CHROMIUM AND VANADIUM [J].

BACHMANN, B ;

HAHN, F ;

HECK, J ;

WUNSCH, M .

ORGANOMETALLICS, 1989, 8 (11) :2523-2543

[2] Metal-metal interactions in linked metallocenes [J].

Barlow, S ;

OHare, D .

CHEMICAL REVIEWS, 1997, 97 (03) :637-669

[3] TRANSITION-METAL CARBONYL COMPLEX OF PENTALENE [J].

BROOKES, A ;

GORDON, F ;

HOWARD, J ;

KNOX, SAR ;

WOODWARD, P .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1973, (16) :587-589

[4] CARBONYL-COMPLEXES OF BIS(CYCLOPENTADIENYL)VANADIUM(II) AND BIS(CYCLOPENTADIENYL)VANADIUM(III) - BIS(CYCLOPENTADIENYL)IODOVANADIUM(III), A MODEL COMPOUND FOR QUANTITATIVE ASSESSMENT OF REVERSIBLE CARBON-MONOXIDE COORDINATIVE ADDITION [J].

CALDERAZ.F ;

FACHINET.G ;

FLORIANI, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1974, 96 (11) :3695-3696

[5]

Carlin R. L, 1986, MAGNETOCHEMISTRY

[6] Organometallic pentalene complexes [J].

Cloke, FGN .

PURE AND APPLIED CHEMISTRY, 2001, 73 (02) :233-238

[7]

Cotton F.A., 1993, MULTIPLE BONDS METAL

[8] THE 1ST COMPLEX WITH A SIGMA-2-PI-4 TRIPLE BOND BETWEEN VANADIUM ATOMS IN A LIGAND FRAMEWORK OF FOURFOLD SYMMETRY-[V2((P-CH3C6H4)NC(H)N(P-C6H4CH3))4] [J].

COTTON, FA ;

DANIELS, LM ;

MURILLO, CA .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1992, 31 (06) :737-738

[9] STRUCTURE OF DICYCLOPENTADIENYLPENTACARBONYLDIVANADIUM - NEW EXAMPLE OF GROSSLY UNSYMMETRICAL CARBONYL BRIDGING [J].

COTTON, FA ;

FRENZ, BA ;

KRUCZYNS.L .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1973, 95 (03) :951-952

[10] THE 1ST TRIPLE-DECKER SANDWICH WITH A BRIDGING BENZENE-RING [J].

DUFF, AW ;

JONAS, K ;

GODDARD, R ;

KRAUS, HJ ;

KRUGER, C .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1983, 105 (16) :5479-5480

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