Self-assembly of a 3-D triply interlocked chiral [2]catenane

被引：155

作者：

Westcott, Aleema ^{[1
]}

Fisher, Julie ^{[1
]}

Harding, Lindsay P. ^{[2
]}

Rizkallah, Pierre ^{[3
]}

Hardie, Michaele J. ^{[1
]}

机构：

[1] Univ Leeds, Sch Chem, Leeds LS2 9JT, W Yorkshire, England

[2] Univ Huddersfield, Dept Chem & Biol Sci, Huddersfield HD1 3DH, W Yorkshire, England

[3] STFC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2008年 / 130卷 / 10期

基金：

英国工程与自然科学研究理事会;

关键词：

D O I：

10.1021/ja8002149

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A tripodal cyclotriveratrylene-based ligand with chelating 2,2'-bipyridine arms self-assembles with either Zn(NO3)(2) or Co(NO3)(2) to give 3-D trigonal bipyramidal [M3L2] cage assemblies. These cages triply interlock forming [2]catenane species that have been characterized by mass spectrometry and, in the case of the Zn(II) complex, by X-ray crystallography.

引用

页码：2950 / 2951

页数：2

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