Structural analysis of interfacial layers in Ti/Ta/Al ohmic contacts to n-AlGaN

被引:17
作者
Lim, SH [1 ]
Swider, W [1 ]
Washburn, J [1 ]
Liliental-Weber, Z [1 ]
机构
[1] Univ Calif Berkeley, Lawrence Berkeley Lab, Div Mat Sci, Berkeley, CA 94720 USA
关键词
D O I
10.1063/1.1323517
中图分类号
O59 [应用物理学];
学科分类号
摘要
Detailed structure of the interfacial layers of Ti/Ta/Al ohmic contacts to n-type AlGaN/GaN/ sapphire are investigated by means of transmission electron microscopy. High-resolution electron microscopy (HREM), optical diffractograms, and computer simulations confirmed that TiN (similar to 10.0 nm) and Ti3AlN (similar to1.4 nm) interfacial layers form at the interface between the Ti layer and the Al0.35Ga0.65N substrate by a solid state reaction during annealing for 3 min in N-2 at 950 degreesC. The orientation relationship between Ti3AlN and Al0.35Ga0.65N was found to be: [011](Ti3AlN)parallel to [2 (1) over bar(1) over bar0](Al0.35Ga0.65N) and (1 (1) over bar1)(Ti3AlN)parallel to (0 (0) over bar 01)(Al0.35Ga0.65N). The cubic Ti3AlN interfacial layer, has a lattice parameter of 0.411+/-0.003 nm with the space group Pm3m matching that of Al0.35Ga0.65N A model of the atomic configurations of the Ti3AlN/Al0.35Ga0.65N interface is proposed. This model is supported by a good match between the simulated and the experimental HREM image of the Ti3AlN/Al0.35Ga0.65N interface. The formation of TiN and Ti3AlN interfacial layers appears to be responsible for the onset of the ohmic contact behavior in Ti/Ta/Al contacts. (C) 2000 American Institute of Physics. [S0021-8979(00)04924-0].
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页码:6364 / 6368
页数:5
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