Electrogenerated chemiluminescence triggered by electroseparation of Ru(bpy)32+ across a supported liquid membrane

被引：9

作者：

Crespo, Gaston A. ^{[1
]}

Mistlberger, Guenter ^{[1
]}

Bakker, Eric ^{[1
]}

机构：

[1] Univ Geneva, Dept Inorgan Analyt & Appl Chem, CH-1211 Geneva, Switzerland

来源：

CHEMICAL COMMUNICATIONS | 2011年 / 47卷 / 42期

基金：

瑞士国家科学基金会;

关键词：

ELECTRODE; SENSORS; SYSTEM;

D O I：

10.1039/c1cc14822b

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We demonstrate here for the first time the detection of electrogenerated chemiluminescence (ECL) upon selective, electrochemically triggered tris(2,2'-bipyridyl) ruthenium(II) (Ru(bpy)(3)(2+)) transport across a supported liquid membrane doped with a lipophilic cation-exchanger. This approach allows one to separate the location of ECL generation from the sample compartment, thereby avoiding the contamination of the sample with compounds necessary for ECL.

引用

页码：11644 / 11646

页数：3

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