Self-assembly in gold(I) chemistry: A double-stranded polymer with interstrand aurophilic interactions

被引：60

作者：

Mohr, F ^{[1
]}

Jennings, MC ^{[1
]}

Puddephatt, RJ ^{[1
]}

机构：

[1] Univ Western Ontario, Dept Chem, London, ON N6A 5B7, Canada

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2004年 / 43卷 / 08期

关键词：

gold; macrocycles; polymers; self-assembly; supramolecular chemistry;

D O I：

10.1002/anie.200353127

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Raising the gold standard: Hybrid organic-inorganic side-by-side double-chain polymers have been prepared in which individual polymer chains are connected through the aurophilic interactions of gold (1) centers (see picture). The use of alternative isomers of the monomeric building blocks leads to the formation of dimeric or trimeric complexes.

引用

页码：969 / 971

页数：3

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