Nitrogen-doped porous carbon microspherules as supports for preparing monodisperse nickel nanoparticles

被引:30
作者
Li, FB [1 ]
Qian, QL [1 ]
Yan, F [1 ]
Yuan, GQ [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing 100080, Peoples R China
关键词
carbon microbeads; heat treatment; impregnation; electron microscopy; surface properties;
D O I
10.1016/j.carbon.2005.06.049
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
N-doped porous carbon microspherules were developed through controlled carbonization of the copolymer of vinylidene chloride and acrylonitrite. The carbon precursors were prepared by an inorganic-organic hybrid route. Scanning Electron Microscopy (SEM) and X-ray Photoelectron Spectroscopy (XPS) analysis showed the formation of N-doped carbon spherules. N-2 sorption analysis showed that the resultant carbon materials have a BET surface area of 692 m(2)/g. Nickel nanoparticles supported over them are kept in a well-dispersed state. Electron Probe Microanalysis (EPMA) and Transmission Electron Microscopy (TEM) showed nickel nanoparticles are quite monodisperse. Analysis of XPS spectra of the samples with different surface nitrogen atomic concentration demonstrated that nitrogen species on the carbon surfaces have a great impact on the dispersion state of the mounted metal nanocrystals. (C) 2005 Elsevier Ltd. All rights reserved.
引用
收藏
页码:128 / 132
页数:5
相关论文
共 25 条
  • [11] Preparation and characterization of porous carbon beads and their application in dispersing small metal crystallites
    Li, FB
    Huang, J
    Zou, J
    Pan, PL
    Yuan, GQ
    [J]. CARBON, 2002, 40 (15) : 2871 - 2877
  • [12] NEIMANTSVERDRIE.J, 2000, SPECTROSCOPY CATALYS, P51
  • [13] EVOLUTION OF NITROGEN FUNCTIONALITIES IN CARBONACEOUS MATERIALS DURING PYROLYSIS
    PELS, JR
    KAPTEIJN, F
    MOULIJN, JA
    ZHU, Q
    THOMAS, KM
    [J]. CARBON, 1995, 33 (11) : 1641 - 1653
  • [14] APPLICATION OF CARBON NANOTUBES AS SUPPORTS IN HETEROGENEOUS CATALYSIS
    PLANEIX, JM
    COUSTEL, N
    COQ, B
    BROTONS, V
    KUMBHAR, PS
    DUTARTRE, R
    GENESTE, P
    BERNIER, P
    AJAYAN, PM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (17) : 7935 - 7936
  • [15] Rao CNR, 2002, CHEM-EUR J, V8, P28
  • [16] CATALYTIC ENGINEERING OF CARBON NANOSTRUCTURES
    RODRIGUEZ, NM
    CHAMBERS, A
    BAKER, RTK
    [J]. LANGMUIR, 1995, 11 (10) : 3862 - 3866
  • [17] The role of carbon materials in heterogeneous catalysis
    Rodriguez-Reinoso, F
    [J]. CARBON, 1998, 36 (03) : 159 - 175
  • [18] Schmid G, 2001, NANOSCALE MATERIALS IN CHEMISTRY, P15, DOI 10.1002/0471220620.ch2
  • [19] Synthesis and characterization of supported Co2P nanoparticles by grafting of molecular clusters into mesoporous silica matrixes
    Schweyer-Tihay, F
    Braunstein, P
    Estournès, C
    Guille, JL
    Lebeau, B
    Paillaud, JL
    Richard-Plouet, M
    Rosé, J
    [J]. CHEMISTRY OF MATERIALS, 2003, 15 (01) : 57 - 62
  • [20] TRANSFORMATION OF NITROGEN STRUCTURES IN CARBONIZATION OF MODEL COMPOUNDS DETERMINED BY XPS
    STANCZYK, K
    DZIEMBAJ, R
    PIWOWARSKA, Z
    WITKOWSKI, S
    [J]. CARBON, 1995, 33 (10) : 1383 - 1392