Synthesis of conducting polypyrrole by radiolysis polymerization method

被引：42

作者：

Karim, M. R. ^{[1
]}

Lee, C. J. ^{[1
]}

Lee, M. S. ^{[1
]}

机构：

[1] Kyungpook Natl Univ, Dept Chem, Grad Sch, Taegu 702701, South Korea

来源：

POLYMERS FOR ADVANCED TECHNOLOGIES | 2007年 / 18卷 / 11期

关键词：

radiation; polypyrrole; in situ chemical method; conducting polymers; nanoparticles;

D O I：

10.1002/pat.931

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Conducting polypyrrole (PPy) has been synthesized by the in situ gamma radiation-induced chemical oxidative polymerization method. This method takes advantages of the specialties of radiation-induction, and a highly uniform polymer morphology was obtained. The resultant nano-size polypyrrole particles were characterized by Elemental Analysis, Fourier transform infrared (FT-IR), scanning electron microscope (SEM), transmission electron microscopy (TEM) and X-ray Diffraction (XRD). Measurements of polymer particle sizes were obtained at <500 nm. A standard four-point probe revealed that the chemical synthesis of PPy has a good electrical property. Also thermal stability, checked by Thermal Gravimetric Analysis in air, was ensured by this novel synthesis. Copyright (C) 2007 John Wiley & Sons, Ltd.

引用

页码：916 / 920

页数：5

共 48 条

[1] OPTIMUM REACTION CONDITIONS FOR THE POLYMERIZATION OF PYRROLE BY IRON(III) CHLORIDE IN AQUEOUS-SOLUTION [J].