Electropolymerisable bipyridine ruthenium(II) complexes.: Synthesis and electrochemical characterisation of 4-(3-methoxystyryl)- and 4,4′-di(3-methoxystyryl)-2,2′-bipyridine ruthenium complexes

被引：16

作者：

Aranyos, V

Hjelm, J

Hagfeldt, A

Grennberg, H

机构：

[1] Uppsala Univ, Dept Organ Chem, S-75121 Uppsala, Sweden

[2] Uppsala Univ, Dept Phys Chem, S-75121 Uppsala, Sweden

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 08期

关键词：

D O I：

10.1039/b008697p

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A number of new ruthenium polypyridyl complexes with mono- or di-(3-methoxystyryl) substituted bipyridines have been synthesized. The complexes were characterised by NMR, elemental analysis, UV-vis absorption and emission spectroscopy, and cyclic voltammetry. Electroactive polymer films of these complexes have been prepared both by oxidative and reductive electropolymerisation. The polymers have been characterised by UV-vis absorption spectroscopy and cyclic voltammetry. Possible processes involved in the polymerisation and the structure of the film are discussed.

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页码：1319 / 1325

页数：7

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