Strong emission increase of a dicarboxyterpyridene europium(III) complex in the presence of citrate and hydrogen peroxide

被引：18

作者：

Kozhevnikov, VN ^{[1
]}

Mandl, C

Miltschitzky, S

Duerkop, A

Wolfbeis, OS

Koenig, B

机构：

[1] Univ Ekaterinburg, Dept Chem, Ekaterinburg, Russia

[2] Univ Regensburg, Inst Organ Chem, D-93040 Regensburg, Germany

[3] Univ Regensburg, Inst Analyt Chem Chemo & Biosensors, D-93040 Regensburg, Germany

来源：

INORGANICA CHIMICA ACTA | 2005年 / 358卷 / 07期

基金：

俄罗斯基础研究基金会;

关键词：

europium complexes; luminescent probes; citrate sensing;

D O I：

10.1016/j.ica.2005.01.015

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A substituted 6,6"-dicarboxy-2,2':6',2"-terpyridene europium (III) complex (I) responds with an emission wavelength shift and intensity increase to the presence of citrate and hydrogen peroxide, while many oxoanions show no effect. (c) 2005 Elsevier B.V. All rights reserved.

引用

收藏

页码：2445 / 2448

页数：4

相关论文

共 13 条

[1] EUROPIUM CHELATE LABELS IN TIME-RESOLVED FLUORESCENCE IMMUNOASSAYS AND DNA HYBRIDIZATION ASSAYS [J].

DIAMANDIS, EP ;

CHRISTOPOULOS, TK .

ANALYTICAL CHEMISTRY, 1990, 62 (22) :A1149-+

[2] Reversible anion binding in aqueous solution at a cationic heptacoordinate lanthanide centre: selective bicarbonate sensing by time-delayed luminescence [J].

Dickins, RS ;

Gunnlaugsson, T ;

Parker, D ;

Peacock, RD .

CHEMICAL COMMUNICATIONS, 1998, (16) :1643-1644

[3] Time-resolved fluorometry: an overview of the labels and core technologies for drug screening applications [J].

Hemmila, I ;

Webb, S .

DRUG DISCOVERY TODAY, 1997, 2 (09) :373-381

[4]

HEMMILA I, 1991, APPL FLUORESCENCE IM, P215

[5] A new route to 6,6"-dicyano-2,2′:6′,2"-terpyridines and their complexes with Ni(II) [J].

Kozhevnikov, DN ;

Kozhenvikov, VN ;

Nikitina, TV ;

Rusinov, VL ;

Chupakhin, ON ;

Eremenko, IL ;

Aleksandrov, GG .

TETRAHEDRON LETTERS, 2002, 43 (28) :4923-4925

[6] A versatile strategy for the synthesis of functionalized 2,2′-bi- and 2,2′:6′,2"-terpyridines via their 1,2,4-triazine analogues [J].

Kozhevnikov, VN ;

Kozhevnikov, DN ;

Nikitina, TV ;

Rusinov, VL ;

Chupakhin, ON ;

Zabel, M ;

König, B .

JOURNAL OF ORGANIC CHEMISTRY, 2003, 68 (07) :2882-2888

[7] Synthesis of functionalized fluorescent europium(III) terpyridyl chelates [J].

Kozhevnikov, VN ;

Kozhevnikov, DN ;

Rusinov, VL ;

Chupakhin, ON ;

König, B .

SYNTHESIS-STUTTGART, 2003, (15) :2400-2404

[8]

MATHIS G, 1993, CLIN CHEM, P1196

[9] THE SYNTHESIS AND USE OF ACTIVATED N-BENZYL DERIVATIVES OF DIETHYLENETRIAMINETETRAACETIC ACIDS - ALTERNATIVE REAGENTS FOR LABELING OF ANTIBODIES WITH METAL-IONS [J].

MUKKALA, VM ;

MIKOLA, H ;

HEMMILA, I .

ANALYTICAL BIOCHEMISTRY, 1989, 176 (02) :319-325

[10] DEVELOPMENT OF LUMINESCENT EUROPIUM(III) AND TERBIUM(III) CHELATES OF 2,2'/6',2''-TERPYRIDINE DERIVATIVES FOR PROTEIN LABELING [J].

MUKKALA, VM ;

HELENIUS, M ;

HEMMILA, I ;

KANKARE, J ;

TAKALO, H .

HELVETICA CHIMICA ACTA, 1993, 76 (03) :1361-1378