rare-earth metal triflates;
aqueous phase;
ionic liquids;
super critical CO2;
solvent free;
solid support;
organic synthesis;
Green chemistry;
D O I:
10.2174/1570193053544472
中图分类号:
O62 [有机化学];
学科分类号:
070303 [有机化学];
081704 [应用化学];
摘要:
Rare-earth metal triflates have been well established as potent environmentally-benign Lewis acids. This review summarizes the recent progress of RE(OTf)(3) catalyzed organic synthesis in green media including water, ionic liquids, super critical CO2, solvent-free conditions as well as solid supported synthesis.