Aqueous hypervalent silicon complexes with aliphatic sugar acids

被引：65

作者：

Kinrade, SD

Hamilton, RJ

Schach, AS

Knight, CTG

机构：

[1] Lakehead Univ, Dept Chem, Thunder Bay, ON P7B 5E1, Canada

[2] Univ Illinois, Sch Chem Sci, Urbana, IL 61801 USA

来源：

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS | 2001年 / 07期

关键词：

D O I：

10.1039/b010111g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Silicon-29 and carbon-13 NMR spectroscopy is employed to determine the structures of stable five- and six-coordinated organosilicon complexes formed by the addition of certain aliphatic acid carbohydrates (such as gluconic acid, glucoheptonic acid and saccharic acid) to aqueous alkaline silicate solutions.

引用

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页码：961 / 963

页数：3

相关论文

共 14 条

[1]

BURGER K, 1990, P236

[2] COMPLEXATION OF ALUMINUM(III), GALLIUM(III) AND INDIUM(III) IONS WITH D-GLUCONIC AND LACTOBIONIC ACIDS - A POTENTIOMETRIC AND NUCLEAR-MAGNETIC-RESONANCE SPECTROSCOPIC STUDY [J].

ESCANDAR, GM ;

OLIVIERI, AC ;

GONZALEZSIERRA, M ;

FRUTOS, AA ;

SALA, LF .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1995, (05) :799-804

[3] NUCLEAR-MAGNETIC-RESONANCE STUDIES OF SILICON(IV) COMPLEXES IN AQUEOUS-SOLUTION .2. TRIS-TROPOLONATO AND TRIS-3-HYDROXYPYRIDIN-4-ONATO COMPLEXES [J].

EVANS, DF ;

PARR, J ;

WONG, CY .

POLYHEDRON, 1992, 11 (05) :567-572

[4] N-OXIDES AND RELATED COMPOUNDS .5. THE TAUTOMERISM OF 2-AMINO AND 4-AMINO- AND 2-HYDROXY-PYRIDINE AND-4-HYDROXY-PYRIDINE 1-OXIDE [J].

GARDNER, JN ;

KATRITZKY, AR .

JOURNAL OF THE CHEMICAL SOCIETY, 1957, (OCT) :4375-4385

[5] 5-COORDINATE SI COMPOUNDS AS INTERMEDIATES IN THE SYNTHESIS OF SILICATES IN NONAQUEOUS MEDIA [J].

HERREROS, B ;

CARR, SW ;

KLINOWSKI, J .

SCIENCE, 1994, 263 (5153) :1585-1587

[6] Stable five- and six-coordinated silicate anions in aqueous solution [J].

Kinrade, SD ;

Del Nin, JW ;

Schach, AS ;

Sloan, TA ;

Wilson, KL ;

Knight, CTG .

SCIENCE, 1999, 285 (5433) :1542-1545

[7] Silicon-29 NMR evidence of alkoxy substituted aqueous silicate anions [J].

Kinrade, SD ;

Maa, KJ ;

Schach, AS ;

Sloan, TA ;

Knight, CTG .

JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (18) :3149-3150

[8] BORATE ESTERS OF ALDITOLS - SYNTHESIS, STRUCTURE AND STABILITY IN AQUEOUS-SOLUTION [J].

MUNOZ, A ;

LAMANDE, L .

CARBOHYDRATE RESEARCH, 1992, 225 (01) :113-121

[9] The regulation of mineral absorption in the gastrointestinal tract [J].

Powell, JJ ;

Jugdaohsingh, R ;

Thompson, RPH .

PROCEEDINGS OF THE NUTRITION SOCIETY, 1999, 58 (01) :147-153

[10] EQUILIBRIUM AND STRUCTURAL STUDIES OF SILICON(IV) AND ALUMINUM(III) IN AQUEOUS-SOLUTION .31. AQUEOUS COMPLEXATION BETWEEN SILICIC-ACID AND THE CATECHOLAMINES DOPAMINE AND L-DOPA [J].

SEDEH, IF ;

SJOBERG, S ;

OHMAN, LO .

JOURNAL OF INORGANIC BIOCHEMISTRY, 1993, 50 (02) :119-132