Laminated Graphene Films for Flexible Transparent Thin Film Encapsulation

被引:81
作者
Seo, Hong-Kyu [1 ]
Park, Min-Ho [1 ]
Kim, Young-Hoon [1 ]
Kwon, Sung-Joo [1 ]
Jeong, Su-Hun [1 ]
Lee, Tae-Woo [1 ]
机构
[1] Pohang Univ Sci & Technol POSTECH, Dept Mat Sci & Engn, Pohang 790784, Gyungbuk, South Korea
基金
新加坡国家研究基金会;
关键词
graphene; flexible lamination encapsulation; polymer light emitting diodes (PLED); lifetime; water vapor transmission rate (WVTR); LIGHT-EMITTING DEVICES; ATOMIC LAYER DEPOSITION; GAS BARRIER FILMS; PERMEATION; PERFORMANCE; ELECTRODES; OXIDE; MEMBRANES; COATINGS; DIODES;
D O I
10.1021/acsami.6b01639
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
We introduce a simple, inexpensive, and large area flexible transparent lamination encapsulation method that uses graphene films with polydimethylsiloxane (PDMS) buffer on polyethylene terephthalate (PET) substrate. The number Of stacked graphene layers (n(G)) was increased from 2 to 6, and 6-layered graphene-encapsulation showed high impermeability to moisture and air. The graphene-encapsulated polymer light emitting diodes (PLEDs) had stable operating characteristics; and the operational lifetime of encapsulated PLEDs increased as nG increased. Calcium oxidation test data confirmed the improved impermeability of graphene-encapsulation with increased nG. As a practical application, we demonstrated large-area flexible organic light emitting diodes (FOLEDs) and transparent FOLEDs that were encapsulated by our polymer/graphene encapsillant.
引用
收藏
页码:14725 / 14731
页数:7
相关论文
共 36 条
[1]  
Bae S, 2010, NAT NANOTECHNOL, V5, P574, DOI [10.1038/NNANO.2010.132, 10.1038/nnano.2010.132]
[2]   Implications of Permeation through Intrinsic Defects in Graphene on the Design of Defect-Tolerant Membranes for Gas Separation [J].
Boutilier, Michael S. H. ;
Sun, Chengzhen ;
O'Hern, Sean C. ;
Au, Harold ;
Hadjiconstantinou, Nicolas G. ;
Karnik, Rohit .
ACS NANO, 2014, 8 (01) :841-849
[3]   Impermeable atomic membranes from graphene sheets [J].
Bunch, J. Scott ;
Verbridge, Scott S. ;
Alden, Jonathan S. ;
van der Zande, Arend M. ;
Parpia, Jeevak M. ;
Craighead, Harold G. ;
McEuen, Paul L. .
NANO LETTERS, 2008, 8 (08) :2458-2462
[4]   RELIABILITY AND DEGRADATION OF ORGANIC LIGHT-EMITTING DEVICES [J].
BURROWS, PE ;
BULOVIC, V ;
FORREST, SR ;
SAPOCHAK, LS ;
MCCARTY, DM ;
THOMPSON, ME .
APPLIED PHYSICS LETTERS, 1994, 65 (23) :2922-2924
[5]   Graphenes Converted from Polymers [J].
Byun, Sun-Jung ;
Lim, Hyunseob ;
Shin, Ga-Young ;
Han, Tae-Hee ;
Oh, Sang Ho ;
Ahn, Jong-Hyun ;
Choi, Hee Cheul ;
Lee, Tae-Woo .
JOURNAL OF PHYSICAL CHEMISTRY LETTERS, 2011, 2 (05) :493-497
[6]   Evaluation of gas permeation barrier properties using electrical measurements of calcium degradation [J].
Choi, Jin Hwan ;
Kim, Young Min ;
Park, Young Wook ;
Huh, Jin Woo ;
Ju, Byeong Kwon ;
Kim, In Sun ;
Hwang, Hee Nam .
REVIEW OF SCIENTIFIC INSTRUMENTS, 2007, 78 (06)
[7]   Reduced Water Vapor Transmission Rate of Graphene Gas Barrier Films for Flexible Organic Field-Effect Transistors [J].
Choi, Kyoungjun ;
Nam, Sooji ;
Lee, Youngbin ;
Lee, Mijin ;
Jang, Jaeyoung ;
Kim, Sang Jin ;
Jeong, Yong Jin ;
Kim, Hyeongkeun ;
Bae, Sukang ;
Yoo, Ji-Beom ;
Cho, Sung M. ;
Choi, Jae-Boong ;
Chung, Ho Kyoon ;
Ahn, Jong-Hyun ;
Park, Chan Eon ;
Hong, Byung Hee .
ACS NANO, 2015, 9 (06) :5818-5824
[8]   Gas diffusion barriers on polymers using multilayers fabricated by Al2O3 and rapid SiO2 atomic layer deposition [J].
Dameron, Arrelaine A. ;
Davidson, Stephen D. ;
Burton, Beau B. ;
Carcia, Peter F. ;
McLean, R. Scott ;
George, Steven M. .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (12) :4573-4580
[9]   Raman spectrum of graphene and graphene layers [J].
Ferrari, A. C. ;
Meyer, J. C. ;
Scardaci, V. ;
Casiraghi, C. ;
Lazzeri, M. ;
Mauri, F. ;
Piscanec, S. ;
Jiang, D. ;
Novoselov, K. S. ;
Roth, S. ;
Geim, A. K. .
PHYSICAL REVIEW LETTERS, 2006, 97 (18)
[10]   The rise of graphene [J].
Geim, A. K. ;
Novoselov, K. S. .
NATURE MATERIALS, 2007, 6 (03) :183-191