Palladium catalysed regio and stereoselective reduction of Baylis-Hillman coupling products derived allylic acetates

被引：26

作者：

Pachamuthu, K ^{[1
]}

Vankar, YD ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 30期

关键词：

D O I：

10.1016/S0040-4039(98)01049-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Acetates derived front a variety of the Baylis-Hillman products undergo reduction with HCOOH in the presence of Et3N. Pd(OAc)(2), and dppe (or tri-isopropylphosphite) to yield the corresponding trisubstituted Z-olefins in good yields displaying high regio and stereoselectivity. (C) 1998 Published by Elsevier Science Ltd. All lights reserved.

引用

页码：5439 / 5442

页数：4

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