Nanostructured electrodes and the low-temperature performance of Li-ion batteries

被引:243
作者
Sides, CR
Martin, CR [1 ]
机构
[1] Univ Florida, Dept Chem, Gainesville, FL 32611 USA
[2] Univ Florida, Ctr Res Bio Nano Interface, Gainesville, FL 32611 USA
关键词
D O I
10.1002/adma.200400517
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Template-synthesized V2O5 nano- structured electrodes (see Figure and cover) are used as tools for fundamental investigations into the poor low-temperature performance of Li-ion batteries. The electrodes consisted of nanofibers of V2O5, and by controlling the dimensions of the nanofibers it has been determined that the rate-limiting factor at low temperatures is the concentration polarization of the Li ion in the electrode material.
引用
收藏
页码:125 / +
页数:5
相关论文
共 25 条
[1]   An analysis of rechargeable lithium-ion batteries after prolonged cycling [J].
Aurbach, D ;
Markovsky, B ;
Rodkin, A ;
Cojocaru, M ;
Levi, E ;
Kim, HJ .
ELECTROCHIMICA ACTA, 2002, 47 (12) :1899-1911
[2]   Chemical-vapor deposition-based template synthesis of microtubular TiS2 battery electrodes [J].
Che, G ;
Jirage, KB ;
Fisher, ER ;
Martin, CR ;
Yoneyama, H .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 1997, 144 (12) :4296-4302
[3]   Nanocomposite polymer electrolytes for lithium batteries [J].
Croce, F ;
Appetecchi, GB ;
Persi, L ;
Scrosati, B .
NATURE, 1998, 394 (6692) :456-458
[4]   THE LIXV2O5 SYSTEM - AN OVERVIEW OF THE STRUCTURE MODIFICATIONS INDUCED BY THE LITHIUM INTERCALATION [J].
DELMAS, C ;
COGNACAURADOU, H ;
COCCIANTELLI, JM ;
MENETRIER, M ;
DOUMERC, JP .
SOLID STATE IONICS, 1994, 69 (3-4) :257-264
[5]  
Ehrlich G.M., 2002, HDB BATTERIES
[6]   Influence of carbon black and binder on Li-ion batteries [J].
Fransson, L ;
Eriksson, T ;
Edström, K ;
Gustafsson, T ;
Thomas, JO .
JOURNAL OF POWER SOURCES, 2001, 101 (01) :1-9
[7]   Runaway risk of forming toxic compounds [J].
Hammami, A ;
Raymond, N ;
Armand, M .
NATURE, 2003, 424 (6949) :635-636
[8]   The limits of low-temperature performance of Li-ion cells [J].
Huang, CK ;
Sakamoto, JS ;
Wolfenstine, J ;
Surampudi, S .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2000, 147 (08) :2893-2896
[9]   A high-rate, high-capacity, nanostructured Sn-based anode prepared using sol-gel template synthesis [J].
Li, NC ;
Martin, CR .
JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2001, 148 (02) :A164-A170
[10]   Low-temperature behavior of Li-ion cells [J].
Lin, HP ;
Chua, D ;
Salomon, M ;
Shiao, HC ;
Hendrickson, M ;
Plichta, E ;
Slane, S .
ELECTROCHEMICAL AND SOLID STATE LETTERS, 2001, 4 (06) :A71-A73