Floating single hydrogen molecule in an open-cage fullerene

被引：25

作者：

Sawa, H ^{[1
]}

Wakabayashi, Y

Murata, Y

Murata, M

Komatsu, K

机构：

[1] High Energy Accelerator Res Org, Inst Mat Struct Sci, Tsukuba, Ibaraki 3050801, Japan

[2] Kyoto Univ, Inst Chem Res, Uji, Kyoto 6110011, Japan

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2005年 / 44卷 / 13期

关键词：

cage compounds; fullerenes; host-guest systems; hydrogen; X-ray diffraction;

D O I：

10.1002/anie.200462850

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Open-mouthed fullerene swallows H2 whole: Direct observation of a H2 molecule that is fully encapsulated by a derivative of an aza-thia open-cage fullerene (see model) is achieved by synchrotron X-ray diffraction analysis of single crystals. A 3D electron-density map obtained by the maximum entropy method shows a single H2 molecule (red) floating in the center of a hollow cavity in the open-cage fullerene molecule (yellow). © 2005 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：1981 / 1983

页数：3

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