Synthesis and catalytic activity of a chiral periodic mesoporous organosilica (ChiMO)

被引：173

作者：

Baleizao, C

Gigante, B

Das, D

Alvaro, M

Garcia, H

Corma, A

机构：

[1] CSIC, Inst Tecnol Quim, Valencia 46022, Spain

[2] INETI, Dept Tecnol Ind Quim, P-1649038 Lisbon, Portugal

来源：

CHEMICAL COMMUNICATIONS | 2003年 / 15期

关键词：

D O I：

10.1039/b304814d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A chiral vanadyl salen complex having two peripheral trimethoxysilyl groups has been used to obtain a chiral periodic mesoporous organosilica having MCM-41 periodicity and the two Si-CH2 groups anchored on the framework; this solid induces 30% enantioselectivity in the cyanosilylation of benzaldehyde.

引用

页码：1860 / 1861

页数：2

共 11 条

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