Hollow polymeric nanostructures-Synthesis, morphology and function

被引:184
作者
Fu, Guo-Dong [1 ]
Li, Guo Liang [2 ]
Neoh, K. G. [2 ]
Kang, E. T. [2 ]
机构
[1] Southeast Univ, Sch Chem & Chem Engn, Nanjing 211189, Peoples R China
[2] Natl Univ Singapore, Dept Chem & Biomol Engn, Singapore 119260, Singapore
基金
中国国家自然科学基金;
关键词
Polymer; Hollow nanospheres; Nanotubes; Synthesis; Morphology; Functions; BLOCK-COPOLYMER VESICLES; TRANSFER RADICAL POLYMERIZATION; POLYPEPTIDE DIBLOCK COPOLYMERS; WATER-IN-OIL; MAGNETITE/POLYSTYRENE NANOCOMPOSITE MICROSPHERES; MEMBRANE EMULSIFICATION TECHNIQUE; ELECTROCHEMICAL HYDROGEN STORAGE; METHYL METHACRYLATE COPOLYMERS; CONSTANT FLUOROPOLYMER FILMS; CORE-SHELL NANOSTRUCTURES;
D O I
10.1016/j.progpolymsci.2010.07.011
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 [高分子化学与物理];
摘要
The development of reliable synthetic routes to polymeric nanostructures of well-defined composition, morphology and function is of scientific importance and technological interest. The generation of functional hollow polymeric nanostructures, hollow nanospheres and nanotubes in particular, can be achieved through direct and template-directed synthesis, core-shell precursors, and self-assembly of copolymers and polymer conjugates, as well as from dendrimers. The ability to prepare precursor macromolecules of well-defined structure and architecture has been substantially enhanced by recent advances in controlled radical polymerizations. The application and potential application of the hollow polymeric nanospheres and nanotubes as nanoreactors, and in diagnostics, encapsulation, controlled release, and other stimuli-responsive systems are also described. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:127 / 167
页数:41
相关论文
共 423 条
[1]
Conducting-polymer nanotubes for controlled drug release [J].
Abidian, MR ;
Kim, DH ;
Martin, DC .
ADVANCED MATERIALS, 2006, 18 (04) :405-+
[2]
Fluorogenic polydiacetylene supramolecules: Immobilization, micropatterning, and application to label-free chemosensors [J].
Ahn, Dong June ;
Kim, Jong-Man .
ACCOUNTS OF CHEMICAL RESEARCH, 2008, 41 (07) :805-816
[3]
Synthesis, characterization, and manipulation of nitrogen-doped carbon nanotube cups [J].
Allen, Brett L. ;
Kichambare, Padmakar D. ;
Star, Alexander .
ACS NANO, 2008, 2 (09) :1914-1920
[4]
Single-molecular-system-based selective micellar templates for polyaniline nanomaterials: Control of shape, size, solid state ordering, and expanded chain to coillike conformation [J].
Anilkumar, P. ;
Jayakannan, M. .
MACROMOLECULES, 2007, 40 (20) :7311-7319
[5]
[Anonymous], 2005, Block Copolymers in Solution
[6]
Vesicles and liposomes:: A self-assembly principle beyond lipids [J].
Antonietti, M ;
Förster, S .
ADVANCED MATERIALS, 2003, 15 (16) :1323-1333
[7]
Polymer-vesicle association [J].
Antunes, Filipe E. ;
Marques, Eduardo F. ;
Miguel, Maria G. ;
Lindman, Bjoern .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 2009, 147-48 :18-35
[8]
Chiral salen complexes: An overview to recoverable and reusable homogeneous and heterogeneous catalysts [J].
Baleizao, Carlos ;
Garcia, Hermenegildo .
CHEMICAL REVIEWS, 2006, 106 (09) :3987-4043
[9]
Co-electrospinning of core-shell fibers using a single-nozzle technique [J].
Bazilevsky, Alexander V. ;
Yarin, Alexander L. ;
Megaridis, Constantine M. .
LANGMUIR, 2007, 23 (05) :2311-2314
[10]
Cell-specific integration of artificial organelles based on functionalized polymer vesicles [J].
Ben-Haim, Nadav ;
Broz, Pavel ;
Marsch, Stephan ;
Meier, Wolfgang ;
Hunziker, Patrick .
NANO LETTERS, 2008, 8 (05) :1368-1373