State-of-the-Art Catalysts for Hydrogenation of Carbon Dioxide

被引：417

作者：

Federsel, Christopher ^{[1
]}

Jackstell, Ralf ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, LIKAT, D-18059 Rostock, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 36期

关键词：

atmospheric chemistry; carbon dioxide fixation; homogeneous catalysis; hydrogenation; reduction; FORMIC-ACID DECOMPOSITION; HOMOGENEOUS HYDROGENATION; PINCER COMPLEXES; GENERATION; CONVERSION; H-2; ALCOHOLS; ACTIVATION; LIGANDS; STORAGE;

D O I：

10.1002/anie.201000533

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Efficiency is key: Nozaki and co-workers managed to achieve very high turnover numbers for the reduction of carbon dioxide to formic acid using an active Iridium(III)-pincer complex 1. This Highlight compares Nozaki's work to previously reported state-of-the-art catalysts. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：6254 / 6257

页数：4

共 62 条

[1]

Albrecht M, 2001, ANGEW CHEM INT EDIT, V40, P3750, DOI 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO

[2]

2-6

[3]

Albrecht M., 2001, ANGEW CHEM, V113, P3866, DOI DOI 10.1002/1521-3773(20011015)113:20<3866::AID-ANGE3866>3.0.C0

[4]

2-Y

[5] Complexes [(P-2)Rh(hfacac)] as model compounds for the fragment [(P-2)Rh] and as highly active catalysts for CO2 hydrogenation: The accessible molecular surface (AMS) model as an approach to quantifying the intrinsic steric properties of chelating ligands in homogeneous catalysis [J].

Angermund, K ;

Baumann, W ;

Dinjus, E ;

Fornika, R ;

Gorls, H ;

Kessler, M ;

Kruger, C ;

Leitner, W ;

Lutz, F .

CHEMISTRY-A EUROPEAN JOURNAL, 1997, 3 (05) :755-764

[6]

[Anonymous], 2006, ANGEW CHEM, DOI DOI 10.1002/ANGE.200503771

[7]

[Anonymous], 2009, NATURE

[8]

[Anonymous], 1995, Angew. Chem., DOI DOI 10.1002/ANGE.19951072005

[9]

[Anonymous], 2008, ANGEW CHEM-GER EDIT

[10]

Aresta M., 2003, Carbon dioxide recovery and utilization, P407

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