State-of-the-Art Catalysts for Hydrogenation of Carbon Dioxide

被引:417
作者
Federsel, Christopher [1 ]
Jackstell, Ralf [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, LIKAT, D-18059 Rostock, Germany
关键词
atmospheric chemistry; carbon dioxide fixation; homogeneous catalysis; hydrogenation; reduction; FORMIC-ACID DECOMPOSITION; HOMOGENEOUS HYDROGENATION; PINCER COMPLEXES; GENERATION; CONVERSION; H-2; ALCOHOLS; ACTIVATION; LIGANDS; STORAGE;
D O I
10.1002/anie.201000533
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Efficiency is key: Nozaki and co-workers managed to achieve very high turnover numbers for the reduction of carbon dioxide to formic acid using an active Iridium(III)-pincer complex 1. This Highlight compares Nozaki's work to previously reported state-of-the-art catalysts. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:6254 / 6257
页数:4
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