A viable hydrogen-storage system based on selective formic acid decomposition with a ruthenium catalyst

被引：525

作者：

Fellay, Celine ^{[1
]}

Dyson, Paul J. ^{[1
]}

Laurenczy, Gabor ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Inst Sci & Ingn Chim, CH-1015 Lausanne, Switzerland

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 21期

关键词：

formic acid; homogeneous catalysis; hydrogen storage; ruthenium;

D O I：

10.1002/anie.200800320

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Chemical Equation Presented) The use of formic acid as a hydrogen-storage material has become more feasible thanks to the development of a homogeneous catalytic system of ruthenium water-soluble complexes (Ru/TPPTS; TPPTS = meta-trisulfonated triphenylphosphine) that selectively decomposes HCOOH into H2 and CO2. Continuous generation of H2 of very high purity, over a wide range of pressures, and under mild conditions was achieved. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3966 / 3968

页数：3

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