High-pressure polymorphism as a step towards destabilization of LiBH4

被引：105

作者：

Filinchuk, Yaroslav ^{[1
]}

Chernyshov, Dmitry ^{[1
,3
]}

Nevidomskyy, Andriy ^{[2
]}

Dmitriev, Vladimir ^{[1
]}

机构：

[1] Swiss Norwegian Beam Lines ESRF, F-38043 Grenoble, France

[2] Univ Sherbrooke, Dept Phys, Sherbrooke, PQ J1K 2R1, Canada

[3] St Petersburg State Univ, Fac Geol, Dept Crystallog, St Petersburg 199034, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 03期

关键词：

high pressure; hydrides; polymorphism; structure elucidation; X-ray diffraction;

D O I：

10.1002/anie.200704777

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Performing under pressure: The BH4 group in the high-pressure modification of LiBH4 has an unprecedented square-planar coordination by four Li atoms (see picture). This structure exhibits a strikingly short H⋯H contact between adjacent BH4 anions and thus may show completely different hydrogen-storage properties if stabilized by chemical substitution at ambient pressure. (Figure Presented) © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：529 / 532

页数：4

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