Rhodium complex-catalysed allylic alkylation of allylic acetates

被引：31

作者：

Takeuchi, R ^{[1
]}

Kitamura, N ^{[1
]}

机构：

[1] Yokohama City Univ, Fac Sci, Dept Environm Sci, Kanazawa Ku, Yokohama, Kanagawa 2360027, Japan

来源：

NEW JOURNAL OF CHEMISTRY | 1998年 / 22卷 / 07期

关键词：

D O I：

10.1039/a802876a

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

[Rh(COD)Cl](2)-P(OPh)(3) (P : Rh = 2-3) is found to be an efficient catalyst for allylic alkylation of allylic acetates with a stabilized carbon nucleophile; alkylation at the more substituted allylic terminus is predominant.

引用

页码：659 / 660

页数：2

共 14 条

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