Synthesis of huge macrocycles using two calix[4]arenes as templates

被引：32

作者：

Cao, YD ^{[1
]}

Wang, LY

Bolte, M

Vysotsky, MO

Böhmer, V

机构：

[1] Johannes Gutenberg Univ Mainz, Abt Lehramt Chem, Fachbereich Chem Pharm & Geowissensch, D-55099 Mainz, Germany

[2] Goethe Univ Frankfurt, Fachbereich Chem & Pharm Wissensch, Inst Organ Chem, D-60439 Frankfurt, Germany

来源：

CHEMICAL COMMUNICATIONS | 2005年 / 25期

关键词：

D O I：

10.1039/b505223h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Macrocycles with up to 100 atoms have been synthesised using two calix[4]arenes as templates: first, (3,5-dialkenyloxy)phenyl groups are attached to the wide rim of a calix[4]arene via urea links, then the alkenyl groups are connected via a metathesis reaction using a tetratosylurea calix[4]arene for their correct prearrangement and finally the urea functions are cleaved to detach the newly formed macrocycles.

引用

页码：3132 / 3134

页数：3

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