Macrocycle synthesis by olefin metathesis on a nanosized, shape-persistent tricationic platinum template

被引：60

作者：

Chuchuryukin, AV

Dijkstra, HP

Suijkerbuijk, BMJM

Gebbink, RJMK

van Klink, GPM

Mills, AM

Spek, AL

van Koten, G

机构：

[1] Univ Utrecht, Debye Inst, Dept Met Mediated Synth, NL-3584 CH Utrecht, Netherlands

[2] Univ Utrecht, Bijvoet Ctr Biomol Res, Dept Crystal & Struct Chem, NL-3584 CH Utrecht, Netherlands

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2003年 / 42卷 / 02期

关键词：

macrocyclic ligands; metathesis; N ligands; platinum; template synthesis;

D O I：

10.1002/anie.200390086

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A 69-membered ring (see picture) results from a metathesis reaction that uses a metalated tris(pincer)-substituted benzene as scaffold. The macrocyclic product can be detached by the addition of Cl after which the template is recovered quantitavely.

引用

页码：228 / +

页数：4

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