Olefin metatheses in metal coordination spheres:: novel trans-spanning bidentate and facially-spanning tridentate macrocyclic phosphine complexes

被引：57

作者：

Bauer, EB

Ruwwe, J

Martín-Alvarez, JM

Peters, TB

Bohling, JC

Hampel, FA

Szafert, S

Lis, T

Gladysz, JA

机构：

[1] Univ Erlangen Nurnberg, Inst Organ Chem, D-91054 Erlangen, Germany

[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

[3] Univ Wroclaw, Dept Chem, PL-50383 Wroclaw, Poland

来源：

CHEMICAL COMMUNICATIONS | 2000年 / 22期

关键词：

D O I：

10.1039/b007405p

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title reaction is applied to square-planar rhodium and platinum complexes with trans PPh2(CH2)(6)CH=CH2 ligands, and square-planar platinum or octahedral tungsten complexes with trans or facial PPh[(CH2)(6)CH=CH2](2) ligands. Ring-closing (poly)macrocyclizations occur.

引用

收藏

页码：2261 / 2262

页数：2

相关论文

共 22 条

[1] BIDENTATE ALKENE CARBENE COMPLEXES OF TUNGSTEN - SYNTHESIS, STRUCTURE, AND REACTIVITY TOWARD ALKENES [J].

ALVAREZ, C ;

PACREAU, A ;

PARLIER, A ;

RUDLER, H .

ORGANOMETALLICS, 1987, 6 (05) :1057-1064

[2] Metal-capped α-cyclodextrins:: the crowning of the oligosaccharide torus with precious metals [J].

Armspach, D ;

Matt, D .

CHEMICAL COMMUNICATIONS, 1999, (12) :1073-1074

[3] Poly(ferrocenylenevinylene) from ring-opening metathesis polymerization of ansa-(vinylene)ferrocene [J].

Buretea, MA ;

Tilley, TD .

ORGANOMETALLICS, 1997, 16 (07) :1507-1510

[4] METAL-TEMPLATED SYNTHESIS OF MACROCYCLIC (TRIPHOSPHINE)MOLYBDENUM COMPLEXES [J].

DIEL, BN ;

BRANDT, PF ;

HALTIWANGER, RC ;

HACKNEY, MLJ ;

NORMAN, AD .

INORGANIC CHEMISTRY, 1989, 28 (14) :2811-2816

[5] Efficient synthesis of a molecular knot by copper(I)-induced formation of the precursor followed by ruthenium(II)-catalysed ring closing metathesis [J].

DietrichBuchecker, C ;

Rapenne, G ;

Sauvage, JP .

CHEMICAL COMMUNICATIONS, 1997, (21) :2053-2054

[6]

Edwards PG, 2000, ANGEW CHEM INT EDIT, V39, P2722, DOI 10.1002/1521-3773(20000804)39:15<2722::AID-ANIE2722>3.0.CO

[7]

2-B

[8]

FURSTNER A, 1998, TOP ORGANOMET CHEM, V1

[9] Organometallic reactivity patterns in fluorocarbons and implications for catalysis:: Synthesis, structure, solubility, and oxidative additions of a fluorous analogue of Vaska's complex, trans-Ir(CO)(Cl)[P(CH2CH2(CF2)5CF3)3]2 [J].

Guillevic, MA ;

Rocaboy, C ;

Arif, AM ;

Horvath, IT ;

Gladysz, JA .

ORGANOMETALLICS, 1998, 17 (04) :707-717

[10] Soluble conjugated polymers that contain ferrocenylene units in the backbone [J].

Heo, RW ;

Somoza, FB ;

Randall, T .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1998, 120 (07) :1621-1622