Organocatalysis through halogen-bond activation

被引：226

作者：

Bruckmann, Angelika ^{[1
]}

Pena, Miguel A. ^{[1
]}

Bolm, Carsten ^{[1
]}

机构：

[1] Rhein Westfal TH Aachen, Inst Organ Chem, D-52056 Aachen, Germany

来源：

SYNLETT | 2008年 / 06期

关键词：

amine synthesis; halogen bonding; imine reduction; organocatalysis; quinoline reduction;

D O I：

10.1055/s-2008-1042935

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Haloperfluoroalkanes have been used as catalysts for the reduction of 2-phenylquinoline to its corresponding 1,2,3,4-tetrahydro derivative using a Hantzsch ester as reductand. The results suggest a substrate activation by halogen bonding.

引用

页码：900 / 902

页数：3

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