A self-assembly approach to fabricate the patterned colloidal crystals with a tunable structure

被引:11
作者
Li, T [1 ]
Xing, RB [1 ]
Huang, WH [1 ]
Han, YC [1 ]
机构
[1] Chinese Acad Sci, Grad Sch, Changchun Inst Appl Chem, State Key Lab Polymer Phys & Chem, Changchun 130022, Peoples R China
基金
中国国家自然科学基金;
关键词
microsphere; pattern; template; capillary forces;
D O I
10.1016/j.colsurfa.2005.06.058
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Several different ordered patterns with silica microspheres, including one-dimensional (1-D) colloidal lines, gradient colloidal arrays and three-dimensional (3-D) colloidal crystals were prepared via adjusting the colloidal concentrations and the prepattern geometry on the substrate. The nucleation and crystallization process of microspheres was revealed. The colloidal patterns were found to grow up from the nucleation sites at the edges of the prepattern to the center of the prepattern channels by a combination of gravity driven sedimentation, evaporation-induced capillary forces (dominant), and a strong interaction including Van der Waals attraction between the prepattern walls and the microspheres. (c) 2005 Published by Elsevier B.V.
引用
收藏
页码:22 / 27
页数:6
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