Nonsupercritically dried silica-alumina aerogels - Effect of gelation pH

Silica-alumina mixed oxide aerogels, with 5, 10, 15, 20, and 25 wt% of alumina in silica, have been synthesized by a hybrid sol-gel technique followed by subcritical drying. The gelation has been carried out under pH values of 3 and 5. pH is a decisive parameter that affects the rate of hydrolysis and condensation of alkoxides. Moreover, it also influences the surface area and porosity features of the final material. The gelation time has been found to be much longer for gels that were gelled at pH 3. Nitrogen sorption studies of the aerogels calcined at 500 degrees C indicate that the mixed oxide aerogels are mesoporous in nature and the gels prepared under a gelation pH of 3 have been found to have higher surface area than the pH 5 counterpart. Transmission electron microscopy and X-ray diffraction analysis have been performed to verify the homogeneity of the mixed oxide aerogel.