Electrochemical study of the lithium insertion mechanism into Li4Ti5O12

被引：7

作者：

Sarciaux, Sylvere ^{[1
]}

La Salle, Annie Le Gal ^{[1
]}

Guyomard, Dominique ^{[1
]}

Piffard, Yves ^{[1
]}

机构：

[1] IMN 2, F-44322 Nantes 3, France

来源：

MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS | 1998年 / 311卷

关键词：

Li(4)Ti(5)O(12); Li insertion; insertion mechanism; chrono-amperometry;

D O I：

10.1080/10587259808042367

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

OCV measurements, cyclic voltammetry and chrono-amperometric measurements have been performed to provide information on the type of mechanism of Li insertion into Li(4)Ti(5)O(12) spinel material. Step-wise potentiodynamic electrochemical techniques allow us to distinguish between a single-phase versus two-phase reaction and to conclude on the type of growing mechanism (nucleation-and-growth or homogeneous growth) and the evolution upon cycling.

引用

页码：63 / 68

页数：6

共 7 条

[1]

Armand M. B., 1980, Materials for Advanced Batteries. Proceedings of a NATO Symposium on Materials for Advanced Batteries, P145

[2]

CHABRE Y, 1993, NATO ADV SCI INST SE, V305, P181

[3]

CHABRE Y, 1996, THERMODYNAMICS KINET

[4] SPINEL ANODES FOR LITHIUM-ION BATTERIES [J].