A saccharinate-iron(II) complex with a free saccharin molecule present, [Fe(phen)3]sac2•sacH•6H2O

被引：20

作者：

Deng, RMK

Simon, S

Dillon, KB

Goeta, AE

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Botswana, Dept Chem, Gaborone, Botswana

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2001年 / 57卷

关键词：

D O I：

10.1107/S0108270100013093

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The crystal structure of the title compound, tris(1,10-phenanthroline-N,N')iron(II) bis[1,2-benzisothiazol-3(2H)onate 1,1-dioxide] 1,2-benzisothiazol-3(2H)-one 1,1-dioxide hexahydrate, [Fe(C12H8N2)(3)](C7H4NO3S)(2).C7H5NO3S . 6H(2)O, at 120 K consists of slightly distorted octahedral [Fe(phen)(3)](2+) cations (phen is 1,10-phenanthroline), two saccharinate anions and a free saccharin molecule, as well as six waters of crystallization. The compound has been confirmed as diamagnetic low-spin iron(II) by magnetic measurements. There is extensive hydrogen bonding leading to a three-dimensional network.

引用

页码：4 / 6

页数：3

共 12 条

[1] THE CHARACTERIZATION OF BOTH THE COORDINATED AND NONCOORDINATED SACCHARINATE ION - THE SYNTHESES AND CRYSTAL-STRUCTURES OF AQUA(2-FORMYLPYRIDINE THIOSEMICARBAZONATO)(SACCHARINATO-N)COPPER(II) HEMIHYDRATE AND 2,2'-BIPYRIDYL-(2-FORMYLPYRIDINE THIOSEMICARBAZONATO)COPPER(II) SACCHARINATE DIHYDRATE [J].