The first manganese(II) compound with the saccharinate ligand present both in the complex cation and as the counter-ion:: [Mn(bipy)2(sac)(H2O)]+•sac-

被引：25

作者：

Dillon, KB

Bilton, C

Howard, JAK

Hoy, VJ

Deng, RMK

Sethatho, DT

机构：

[1] Univ Durham, Dept Chem, Durham DH1 3LE, England

[2] Univ Botswana, Dept Chem, Gaborone, Botswana

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS | 1999年 / 55卷

关键词：

D O I：

10.1107/S0108270198013663

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The structure of the title compound, aqua[1,2-benzisothiazol- 3(2H)-onato 1,1-dioxide-N]bis(2,2'-bipyridine-N,N') manganese(II) 1,2-benzisothiazol-3 (2H)-onate 1,1-dioxide, [Mn(C7H4NSO3)(C10H8N2)(2)(H2O)](C7H4NSO3), consists of [Mn(bipy)(2)(sac)(H2O)](+) cations (bipy = 2,2'-bipyridine; sac = saccharinate, C7H4NO3S) and non-coordinated saccharinate (sac(-)) anions. The Mn-II ion constitutes the centre of a slightly distorted octahedron, with the water molecule hydrogen bonded to the N atom in the saccharinate counter-ion.

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页码：330 / 332

页数：3

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