Solution Processed Vanadium Pentoxide as Charge Extraction Layer for Organic Solar Cells

被引:240
作者
Zilberberg, Kirill [1 ]
Trost, Sara [1 ]
Schmidt, Hans [2 ]
Riedl, Thomas [1 ]
机构
[1] Univ Wuppertal, Inst Elect Devices, D-42119 Wuppertal, Germany
[2] Tech Univ Carolo Wilhelmina Braunschweig, Inst High Frequency Technol, D-38106 Braunschweig, Germany
关键词
TRANSITION-METAL OXIDES; THIN-FILMS; V2O5;
D O I
10.1002/aenm.201100076
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Solution processed V 2O 5 films prepared via a sol-gel technique are used to replace PEDOT:PSS as hole extraction interlayers in polymer:fullerene solar cells. A high work function of 5.6 eV is found for the V 2O 5 layers without any post-processing (annealing or plasma treatment). A power conversion efficiency (PCE) of 3%, comparable to reference devices using PEDOT:PSS is verified. Concomitantly, a substantial improvement in device stability is demonstrated. © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:377 / 381
页数:5
相关论文
共 33 条
[1]   REVIEW OF SOLID-STATE ELECTROCHROMIC COATINGS PRODUCED USING SOL-GEL TECHNIQUES [J].
AGRAWAL, A ;
CRONIN, JP ;
ZHANG, R .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 1993, 31 (01) :9-21
[2]   Electrical properties of V2O5 thin films obtained by atomic layer deposition (ALD) [J].
Badot, JC ;
Mantoux, A ;
Baffier, N ;
Dubrunfaut, O ;
Lincot, D .
JOURNAL OF MATERIALS CHEMISTRY, 2004, 14 (23) :3411-3415
[3]  
Benmoussa M., 2003, Active and Passive Electronic Components, V26, P245, DOI 10.1080/0882751031000116223
[4]   Polymer light-emitting diodes with polyethylene dioxythiophene-polystyrene sulfonate as the transparent anode [J].
Cao, Y ;
Yu, G ;
Zhang, C ;
Menon, R ;
Heeger, AJ .
SYNTHETIC METALS, 1997, 87 (02) :171-174
[5]   Stability of the interface between indium-tin-oxide and poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) in polymer light-emitting diodes [J].
de Jong, MP ;
van IJzendoorn, LJ ;
de Voigt, MJA .
APPLIED PHYSICS LETTERS, 2000, 77 (14) :2255-2257
[6]   OXYGEN EQUILIBRIUM PRESSURE ABOVE V2O5-X OXIDE SYSTEM AT 600-DEGREES-C (X LESS-THAN 0.43) [J].
DZIEMBAJ, R ;
PIWOWARCZYK, J .
JOURNAL OF SOLID STATE CHEMISTRY, 1977, 21 (04) :387-392
[7]   The Role of Transition Metal Oxides in Charge-Generation Layers for Stacked Organic Light-Emitting Diodes [J].
Hamwi, Sami ;
Meyer, Jens ;
Kroeger, Michael ;
Winkler, Thomas ;
Witte, Marco ;
Riedl, Thomas ;
Kahn, Antoine ;
Kowalsky, Wolfgang .
ADVANCED FUNCTIONAL MATERIALS, 2010, 20 (11) :1762-1766
[8]   Indium tin oxide-free semi-transparent inverted polymer solar cells using conducting polymer as both bottom and top electrodes [J].
Hau, Steven K. ;
Yip, Hin-Lap ;
Zou, Jingyu ;
Jen, Alex K. -Y. .
ORGANIC ELECTRONICS, 2009, 10 (07) :1401-1407
[9]   Efficient and Air-Stable Polymer Photovoltaic Devices With WO3-V2O5 Mixed Oxides as Anodic Modification [J].
Huang, Jing-Shun ;
Chou, Chen-Yu ;
Lin, Ching-Fuh .
IEEE ELECTRON DEVICE LETTERS, 2010, 31 (04) :332-334
[10]   Highly efficient organic tandem solar cells using an improved connecting architecture [J].
Janssen, A. G. F. ;
Riedl, T. ;
Hamwi, S. ;
Johannes, H.-H. ;
Kowalsky, W. .
APPLIED PHYSICS LETTERS, 2007, 91 (07)