A "Compartmental" borromean weave coordination polymer exhibiting saturated hydrogen bonding to anions and water cluster inclusion

被引:67
作者
Byrne, Peter [1 ]
Lloyd, Gareth O. [1 ]
Clarke, Nigel [1 ]
Steed, Jonathan W. [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
anion binding; coordination modes; coordination polymers; crystal engineering; secondary building units;
D O I
10.1002/anie.200801556
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Weave done it! The reaction of ligands with binding sites for anions and metal ions with silver nitrate has led to the formation of a series of Borromean weave coordination polymers (each network is color coded in the picture). These possess anion-binding and neutral guest inclusion compartments that are occupied by various solvent molecules. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5761 / 5764
页数:4
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