A "Compartmental" borromean weave coordination polymer exhibiting saturated hydrogen bonding to anions and water cluster inclusion

被引:67
作者
Byrne, Peter [1 ]
Lloyd, Gareth O. [1 ]
Clarke, Nigel [1 ]
Steed, Jonathan W. [1 ]
机构
[1] Univ Durham, Dept Chem, Durham DH1 3LE, England
关键词
anion binding; coordination modes; coordination polymers; crystal engineering; secondary building units;
D O I
10.1002/anie.200801556
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Figure Presented) Weave done it! The reaction of ligands with binding sites for anions and metal ions with silver nitrate has led to the formation of a series of Borromean weave coordination polymers (each network is color coded in the picture). These possess anion-binding and neutral guest inclusion compartments that are occupied by various solvent molecules. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:5761 / 5764
页数:4
相关论文
共 37 条
[31]   Diffusion of water in a nonporous hydrophobic crystal [J].
Thallapally, PK ;
Lloyd, GO ;
Atwood, JL ;
Barbour, LJ .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (25) :3848-3851
[32]   Anion binding by Ag(I) complexes of urea-substituted pyridyl ligands [J].
Turner, DR ;
Smith, B ;
Spencer, EC ;
Goeta, AE ;
Evans, IR ;
Tocher, DA ;
Howard, JAK ;
Steed, JW .
NEW JOURNAL OF CHEMISTRY, 2005, 29 (01) :90-98
[33]   The R21(6) hydrogen-bonded synthon in neutral urea and metal-bound halide systems [J].
Turner, DR ;
Smith, B ;
Goeta, AE ;
Evans, IR ;
Tocher, DA ;
Howard, JAK ;
Steed, JW .
CRYSTENGCOMM, 2004, 6 :633-641
[34]   A modular, self-assembled, separated ion pair binding system [J].
Turner, DR ;
Spencer, EC ;
Howard, JAK ;
Tocher, DA ;
Steed, JW .
CHEMICAL COMMUNICATIONS, 2004, (12) :1352-1353
[35]   Reticular synthesis and the design of new materials [J].
Yaghi, OM ;
O'Keeffe, M ;
Ockwig, NW ;
Chae, HK ;
Eddaoudi, M ;
Kim, J .
NATURE, 2003, 423 (6941) :705-714
[36]   Formation of two (6,3) networks showing structural diversity, Borromean topology and conformational chirality in the same crystal [J].
Zhang, Xue-Li ;
Guo, Cui-Ping ;
Yang, Qing-Yuan ;
Wang, Wei ;
Liu, Wei-Sheng ;
Kang, Bei-Sheng ;
Su, Cheng-Yong .
CHEMICAL COMMUNICATIONS, 2007, (41) :4242-4244
[37]   Discrete chiral single-crystal microtubes assembled with honeycomb coordination networks showing structural diversity and borromean topology in one single crystal [J].
Zhang, Xue-Li ;
Guo, Cui-Ping ;
Yang, Qing-Yuan ;
Lu, Tong-Bu ;
Tong, Ye-Xiang ;
Su, Cheng-Yong .
CHEMISTRY OF MATERIALS, 2007, 19 (19) :4630-4632