Mixed phosphite-phosphine and phosphinite-phosphine palladacyclic complexes as highly active catalysts for the amination of aryl chlorides

被引：24

作者：

Bedford, RB ^{[1
]}

Blake, ME ^{[1
]}

机构：

[1] Univ Exeter, Sch Chem, Exeter EX4 4QD, Devon, England

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2003年 / 345卷 / 9-10期

关键词：

amination; aryl chlorides; metallacycles; palladium;

D O I：

10.1002/adsc.200303068

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Tri-tert-butylphosphine adducts of ortho-palladated phosphite and phosphinite complexes formed in situ are excellent catalysts for the Buchwald-Hartwig amination of aryl chloride substrates.

引用

页码：1107 / 1110

页数：4

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