Binding of amino acids into a novel multiresponsive ferrocene receptor having an ene backbone

被引：36

作者：

Debroy, P ^{[1
]}

Banerjee, M

Prasad, M

Moulik, SP

Roy, S

机构：

[1] Indian Inst Technol, Dept Chem, Organometall & Catalysis Lab, Kharagpur 721302, W Bengal, India

[2] Jadavpur Univ, Dept Chem, Ctr Surface Sci, Kolkata 700032, W Bengal, India

来源：

ORGANIC LETTERS | 2005年 / 7卷 / 03期

关键词：

D O I：

10.1021/ol0476772

中图分类号：

O62 [有机化学];

学科分类号：

070303 [有机化学]; 081704 [应用化学];

摘要：

Receptor 1 featuring two open arms, multipoint binding sites, and unsaturated linkers on a ferrocene platform shows strong 1:1 binding to unprotected a-amino acids (UV-vis, fluorescence, CV, ITC, NMR, and ESI-MS). NMR and ESI-MS studies suggest an encapsulative binding mode involving the alpha,beta-unsaturated carbonyl residue (site for -NH3+, interaction A) and the terminal -OH groups (she for -COO-, interaction B).

引用

页码：403 / 406

页数：4

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