Synthesis of thiiranes through direct sulfur transfer to cycloalkenes in the thermolysis of a thiophene endoperoxide

被引：14

作者：

Adam, W

Weinkotz, S

机构：

来源：

CHEMICAL COMMUNICATIONS | 1996年 / 02期

关键词：

D O I：

10.1039/cc9960000177

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Thiophene endoperoxide 2, which was prepared by photo-oxygenation of thiophene 1, transfers a sulfur atom to form thiiranes when thermolysed in the presence of cycloalkenes, an unexpectedly efficient process which can be catalysed by the cobalt-tetraphenylporphine complex.

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页码：177 / 178

页数：2

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